Sodium bicarbonate – Assay, Principle, Procedure

Sodium bicarbonate, commonly known as baking soda, is a white crystalline powder with the chemical formula NaHCO₃. Comprising sodium ions and bicarbonate ions, sodium bicarbonate is a salt widely utilized for various purposes. It serves as a leavening agent in baking, neutralizes stomach acid as an antacid, functions as a household cleaning agent, and finds application in certain medical contexts. Its ability to release carbon dioxide gas when heated or exposed to acids contributes to its role in leavening dough and batter in baking. Its mild abrasive and deodorizing properties make it suitable for cleaning and deodorizing purposes. In medical settings, healthcare providers may use sodium bicarbonate to treat certain acid-base imbalances and conditions that necessitate alkalinization of the body.

Assay for Sodium Bicarbonate

The assay for sodium bicarbonate involves determining its content or concentration in a given sample. One common method is acid-base titration. Here’s a basic outline of the titration process:

Principle

Sodium bicarbonate reacts with an acid in a stoichiometric ratio. The endpoint of the titration is reached when all the sodium bicarbonate has reacted with the acid.

Procedure

1. Weighing:

Weigh a sample of sodium bicarbonate accurately.

2. Titration:

Dissolve the weighed sodium bicarbonate in water to make a solution.

Add a suitable indicator to the solution. Phenolphthalein is commonly used, and it changes color in the pH range around 8.2-10.0.

Titrate the sodium bicarbonate solution with a standardized solution of acid (e.g., hydrochloric acid) of known concentration.

3. Endpoint Detection:

Carry out the titration until the indicator’s color changes, signaling that all the sodium bicarbonate has reacted with the acid.

4. Calculation:

The amount of acid used in the titration is then used to calculate the concentration of sodium bicarbonate in the sample.

Calculation Formula:

Note

The normality of the acid is used because sodium bicarbonate has multiple acidic hydrogens.

The molar mass of sodium bicarbonate (NaHCO3) is used to convert moles to grams.

Always follow proper laboratory techniques, safety precautions, and use calibrated equipment when performing assays.

Properties of Sodium Bicarbonate

Chemical Formula: NaHCO3

Physical Form: White crystalline powder

Solubility: Soluble in water

Taste: Slightly alkaline

Odor: Odorless

Melting Point: Decomposes above 50°C (122°F)

pH: Basic (pH around 8.3 in a 0.1 M solution)

Density: 2.20 g/cm³

Medicinal Uses of Sodium Bicarbonate

1. Antacid:

Used as an antacid, sodium bicarbonate neutralizes excess stomach acid, providing relief from conditions such as heartburn, indigestion, and acid reflux.

2. Alkalinizing Agent:

In medical settings, healthcare providers administer it intravenously to treat certain acid-base imbalances and conditions that require systemic alkalinization of the body.

3. Oral Care:

Some toothpaste formulations include sodium bicarbonate for its mild abrasive properties, aiding in the removal of plaque and surface stains.

4. Hydration:

In certain medical situations, healthcare providers may use sodium bicarbonate as part of a rehydration solution to treat dehydration and acidosis.

5. Urinary Alkalinization:

In certain medical situations, healthcare providers may use sodium bicarbonate as part of a rehydration solution to treat dehydration and acidosis.

6. Cleaning Agent:

Due to its mild abrasive and deodorizing properties, people commonly use sodium bicarbonate as a household cleaning agent.

7. Fire Extinguisher:

Some fire extinguishers use sodium bicarbonate as a dry chemical to suppress certain types of fires, especially those involving flammable liquids and electrical equipment. It’s crucial to note that while sodium bicarbonate has various uses, healthcare professionals should guide its medicinal use, as excessive or improper use can lead to complications. The ingestion of large amounts of sodium bicarbonate without medical supervision can result in systemic alkalosis and electrolyte imbalances. Always follow medical advice and product instructions when using sodium bicarbonate for health-related purposes.

Leave a Reply

Your email address will not be published. Required fields are marked *

Wordpress Social Share Plugin powered by Ultimatelysocial
Instagram
Telegram